Festigkeitsberechnungen unter Berücksichtigung elastisch-plastischen Materialverhaltens im Fachsystem COSAR/N

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Angle-resolved Auger spectrum of the N₂ molecule

Angle-resolved Auger electron spectra of N2 have been measured with good statistics at photon energies corresponding to the π* resonance and the σ* shape resonance, below and above the N 1s threshold, respectively. Angular anisotropy is observed in both cases, but disappears as expected far above threshold. Satellite Auger transitions also show some angular anisotropy close to the N 1s threshold. This is attributed to the creation and decay of conjugate shakeup initial states, which have non-ground-state symmetry

Dynamic-explicit finite element simulation of complex problems in civil engineering by parallel computing

The paper deals with the simulation of the non-linear and time dependent behaviour of complex structures in engineering. Such simulations have to provide high accuracy in the prediction of deformations and stability, by taking into account the long term influences of the non-linear behaviour of the material as well as the large deformation and contact conditions. The limiting factors of the computer simulation are the computer run time and the memory requirement during solving large scale problems. To overcome these problems we use a dynamic-explicit time integration procedure for the solution of the semi-discrete equations of motion, which is very suited for parallel processing. In the paper at first we give a brief review of the theoretical background of the mechanical modelling and the dynamic-explicit technique for the solution of the semi-discrete equations of motion. Then the concept of parallel processing will be discussed . A test example concludes the paper

Core Hole Double-Excitation and Atomiclike Auger Decay in N₂

Core hole decay spectra of the free N2 molecule show evidence for hitherto unobserved molecular resonances both below and above the K-shell photoionization threshold. Based on earlier calculations they are assigned to doubly excited neutral states which could not be seen below threshold in recent high resolution absorption spectra because of the more intense core-to-Rydberg excitations. By calculating the Auger spectrum of core-excited nitrogen atoms, we show that the features are atomiclike

Variation of Cross-Section Enhancement in Decay Spectra of CO under Resonant Raman Conditions

We have measured participator and spectator decay at several photon energies within the range of the lifetime-broadened first vibrational component of the C 1s→π* resonance in CO. From the branching ratios it is evident that the resonant enhancement is different for single-hole and two-hole–one-electron states: The maximum in the resonant intensity peaks at different photon energies. It now becomes necessary to calculate energy-dependent transition matrix elements within the lifetime-broadening range

High-resolution C 1s photoelectron spectra of methane

The C 1s partial photoionization cross section and photoelectron angular distribution of methane (CH4) have been measured with high-energy resolution between threshold and 385 eV photon energy. From the analysis of the vibrational fine structure on the C 1s−1 photoelectron line a vibrational energy of 396±2 meV and an equilibrium bond length of 1.039(±0.001) Å for the CH+4 ion have been determined. The lifetime broadening was found to be 83(±10) meV. The weak feature in the photoabsorption cross section just above threshold does not influence the vibrational fine structure in a way typical for a shape resonance. We therefore suggest that it is due to doubly excited states of the type C (1s)−1(Val)−1(Ryd)1a(Ryd)1b, an assignment which is supported by recent Auger decay studies. Measurements of the shakeup structure revealed six satellite lines, one of which increases strongly in intensity at threshold, thus pointing to the existence of a conjugate shakeup process

Origin of aerosol particles in the mid-latitude and subtropical upper troposphere and lowermost stratosphere from cluster analysis of CARIBIC data

The origin of aerosol particles in the upper troposphere and lowermost stratosphere over the Eurasian continent was investigated by applying cluster analysis methods to in situ measured data. Number concentrations of submicrometer aerosol particles and trace gas mixing ratios derived by the CARIBIC (Civil Aircraft for Regular Investigation of the Atmosphere Based on an Instrument Container) measurement system on flights between Germany and South-East Asia were used for this analysis. Four cluster analysis methods were applied to a test data set and their capability of separating the data points into scientifically reasonable clusters was assessed. The best method was applied to seasonal data subsets for summer and winter resulting in five cluster or air mass types: stratosphere, tropopause, free troposphere, high clouds, and boundary layer influenced. Other source clusters, like aircraft emissions could not be resolved in the present data set with the used methods. While the cluster separation works satisfactory well for the summer data, in winter interpretation is more difficult, which is attributed to either different vertical transport pathways or different chemical lifetimes in both seasons. The geographical distribution of the clusters together with histograms for nucleation and Aitken mode particles within each cluster are presented. Aitken mode particle number concentrations show a clear vertical gradient with the lowest values in the lowermost stratosphere (750–2820 particles/cm3 STP, minimum of the two 25% – and maximum of the two 75%-percentiles of both seasons) and the highest values for the boundary-layer-influenced air (4290–22 760 particles/cm3 STP). Nucleation mode particles are also highest in the boundary-layer-influenced air (1260–29 500 particles/cm3 STP), but are lowest in the free troposphere (0–450 particles/cm3 STP). The given submicrometer particle number concentrations represent the first large-scale seasonal data sets for the upper troposphere and lowermost stratosphere over the Eurasian continent